Theory of Magnetic Hyperfine and Zeeman Interactions for Hund's Case (b), Applied to theState of
- 5 August 1967
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review B
- Vol. 160 (1), 35-44
- https://doi.org/10.1103/physrev.160.35
Abstract
The theory of hyperfine interactions in a homonuclear diatomic molecule is re-examined for Hund's coupling case (b). Diagonal and off-diagonal matrix elements among , the fine-structure levels, are explicitly given for an arbitrary electronic state and spin. Expressions for the Zeeman interactions at small magnetic fields are derived, when is no longer a good quantum number. This theory is applied to the state of , and the previous discrepancy between theoretical and experimental values is resolved.
Keywords
This publication has 13 references indexed in Scilit:
- Theory of the Hyperfine Structure of Molecules: Application to 3Π States of Diatomic Molecules Intermediate between Hund's Cases (a) and (b)The Journal of Chemical Physics, 1966
- On the Hyperfine Structure of InH and the Theory of the Hyperfine Structure of Molecules in Hund's Case (C)The Journal of Chemical Physics, 1966
- Hyperfine Splittings andValues of MetastablePhysical Review B, 1966
- Fine Structure Constants of Metastablein theStatePhysical Review B, 1965
- Electron Magnetic Perturbation in Diatomic Molecules of Hund's Case bThe Journal of Chemical Physics, 1964
- Hyperfine Structure of the Hydrogen Molecule in its MetastableStatePhysical Review B, 1962
- Metastable Hydrogen Molecules. II. Fine Structure of ParahydrogenPhysical Review B, 1962
- Spin-Orbit and Spin-Spin Interactions in Diatomic Molecules. I. Fine Structure ofPhysical Review B, 1962
- Metastable Hydrogen MoleculesPhysical Review B, 1960
- Magnetic Hyperfine Structure in Diatomic MoleculesPhysical Review B, 1952