Selective formylation of calix[4]arenes at the ‘upper rim’ and synthesis of new cavitands
- 1 January 1991
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 14,p. 936-937
- https://doi.org/10.1039/c39910000936
Abstract
The direct selective upper rim 1,3-formylation of conformationally rigid calyx[4]arenes is achieved for the first time; the diametrical bis(formyl)calix[4]arene 4 is used as a key intermediate for the synthesis of new cavitands.Keywords
This publication has 14 references indexed in Scilit:
- Inclusion Properties and Host—Guest Interactions of Calixarenes in the Solid StatePublished by Springer Nature ,1991
- Shell closures of tetrabenzyl chloride cavitands with tetrabenzylthiol cavitands provide carceplexes in which one or two guest molecules are incarceratedJournal of the Chemical Society, Chemical Communications, 1990
- Carcerand interiors provide a new phase of matterJournal of the American Chemical Society, 1989
- Host-guest complexation. 47. Carcerands and carcaplexes, the first closed molecular container compoundsJournal of the American Chemical Society, 1988
- Cyclotriveratrylenes and cryptophanesTetrahedron, 1987
- Electrophilic aromatic substitution. 6. A kinetic study of the formylation of aromatics with 1,1-dichloromethyl methyl ether in nitromethaneThe Journal of Organic Chemistry, 1984
- Cavitands: Organic Hosts with Enforced CavitiesScience, 1983
- AROMATIC ALDEHYDES. MESITALDEHYDEOrganic Syntheses, 1967
- Über α‐Halogenäther, XIII. Neue Verfahren zur Darstellung von PhenolaldehydenEuropean Journal of Inorganic Chemistry, 1963
- Über α‐Halogenäther, IV. Synthesen aromatischer Aldehyde mit Dichlormethyl‐alkyläthernEuropean Journal of Inorganic Chemistry, 1960