High-Temperature Spectral Absorption of the 4.3-Micron CO2 Band
- 1 November 1962
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 37 (9), 1955-1961
- https://doi.org/10.1063/1.1733412
Abstract
The absorption coefficients of the ν3, 4.3‐μ CO2 band were measured over a temperature range of about 1200° to 2400°K at various pathlengths. The hot CO2 sample was investigated in the exhaust jet of a small supersonic burner, while the jet composition was obtained using a radiation temperature measurement and a simple thermochemical calculation. The present experimental results are compared with existing experimental values and theoretical calculations. The results indicate that above 2000°K a weak line approximation can be used to describe the absorption or emission of the band. The apparent integrated band intensity of the CO2 fundamental as a function of temperature is also reported and discussed in relation to other measurements.Keywords
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