STEREOCHEMISTRY OF REDUCTION OF KETONES BY COMPLEX METAL HYDRIDES
- 1 October 1958
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 36 (10), 1431-1435
- https://doi.org/10.1139/v58-210
Abstract
The stereochemistry of the reduction of a number of cyclic ketones with complex metal hydrides has been determined. In the absence of any large steric effect in the ketones, the reduction is essentially stereospecific, giving the more stable alcohol.Keywords
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