Hexacovalent Bond Orbitals III
- 1 April 1950
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 18 (4), 510-511
- https://doi.org/10.1063/1.1747671
Abstract
A set of six equivalent orthogonal bond orbitals of trigonal antiprism symmetry are considered. The orbitals are of type snp3d3−n. The strongest orbitals are obtained when n equals 0.8427. These orbitals are only slightly stronger than the octahedral orbitals. The trigonal antiprism orbitals are stronger than the corresponding trigonal prism orbitals. The SF6, [Complex chemical formula], and Fe(CN)6≡ structures are discussed. The relation used for estimating energies is used to estimate bond energies of CH bonds in the structures [Complex chemical formula], and ≡C–H.This publication has 8 references indexed in Scilit:
- Hexacovalent Bond Orbitals IIThe Journal of Chemical Physics, 1950
- Hexacovalent Bond Orbitals IThe Journal of Chemical Physics, 1949
- Dissociation energies of carbon bonds, and resonance energies in hydrocarbon radicalsTransactions of the Faraday Society, 1949
- The Nature of Bond Orbitals in Quadricovalent Complexes of Transition ElementsThe Journal of Chemical Physics, 1948
- Repulsive Forces in Relation to Bond Energies, Distances and Other PropertiesJournal of the American Chemical Society, 1948
- A Quantitative Discussion of Bond OrbitalsJournal of the American Chemical Society, 1937
- Equivalent Chemical Bonds Formed by,, andEigenfunctionsPhysical Review B, 1932
- THE NATURE OF THE CHEMICAL BOND. APPLICATION OF RESULTS OBTAINED FROM THE QUANTUM MECHANICS AND FROM A THEORY OF PARAMAGNETIC SUSCEPTIBILITY TO THE STRUCTURE OF MOLECULESJournal of the American Chemical Society, 1931