Equilibrium in the Exchange of Deuterium between Ammonia and Hydrogen
- 1 January 1953
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 21 (1), 70-72
- https://doi.org/10.1063/1.1698627
Abstract
Equilibrium in the reaction NH3(g)+HD(g)=NH2D(g)+ H2(g) was measured in the temperature range 210°K to 295°K. The results may be expressed by the relation K=0.972 exp 509/T. The zero‐point energy difference between NH3 and NH2D is calculated to be 635±3 cm−1.Keywords
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