Influence of a Magnetic Field on the Electrochemical Rest Potential
Open Access
- 1 January 2006
- journal article
- Published by The Electrochemical Society in Journal of the Electrochemical Society
- Vol. 153 (1), J1-J7
- https://doi.org/10.1149/1.2135207
Abstract
The influence of an external magnetic field on the rest potential of ferromagnetic and nonferromagnetic electrodes is studied. The shift is measured as a function of magnetic field magnitude and direction, pH, electrolyte composition, solution agitation, and electrode roughness. Anodic shifts can be observed not only for ferromagnetic electrodes (iron, cobalt, nickel), but also for nonmagnetic electrodes (zinc, manganese). The essential condition to observe the shift is that the electrode should be actively corroding. An anodic shift is observed when the cathodic corrosion current is mass-transport limited. The primary mechanism for the effect is agitation of the electrolyte near the electrode surface due to Lorentz force acting on the corrosion currents directly, or via the electrokinetic effect. A smaller influence of magnetic field gradient produced by ferromagnetic electrodes is identified.Keywords
This publication has 19 references indexed in Scilit:
- Characteristics of surfaces produced via magnetoelectrolytic depositionProgress in Surface Science, 2001
- Magnetic electrodepositionJournal of Alloys and Compounds, 2001
- Influence of magnetic forces on electrochemical mass transportElectrochemistry Communications, 2001
- Effect of a Magnetic Field on Electrodeposition: Chronoamperometry of Ag, Cu, Zn, and BiJournal of the Electrochemical Society, 2001
- An electro-chemical magnetic field sensorSensors and Actuators A: Physical, 2000
- Is There a Magnetic Field Effect on Electrochemical Kinetics?The Journal of Physical Chemistry A, 2000
- Magnetoconvection Phenomena: A Mechanism for Influence of Magnetic Fields on Electrochemical ProcessesThe Journal of Physical Chemistry B, 1999
- Magnetic Field Effect on Electrode Reactions. I. Effects on the Open-Circuit Potential of Electrodes in Solutions of Different Magnetic Properties.Acta Chemica Scandinavica, 1996
- Magnetic Field Effect on Electrode Reactions. III. Effects on the Anodic Polarization of an Iron Electrode in an Iron(III) Chloride Solution under Potentiostatic Conditions.Acta Chemica Scandinavica, 1996
- Magnetic Field Effect on Electrode Reactions. II. Effects on the Potential of an Iron Electrode in an Iron(III) Chloride Solution under Galvanostatic Conditions.Acta Chemica Scandinavica, 1996