Cation Distribution in the Garnet Eu3Fe1.94Ga3.06O12
- 1 February 1968
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 48 (3), 1094-1096
- https://doi.org/10.1063/1.1668768
Abstract
A single crystal x‐ray diffraction study of the cation distribution in the garnet Eu3Fe1.94Ga3.06 has been made. The greater preference of the Ga3+ions for the tetrahedral sites with respect to the one of the Fe3+ions, already postulated from magnetic measurements, has been confirmed. The fraction f t = 0.91 ± 0.03 of the total Ga3+ in the crystal is found in the tetrahedral sites, while only 0.103 of the total Fe3+ is found in these sites.Keywords
This publication has 12 references indexed in Scilit:
- Oxygen coordinates of compounds with garnet structureActa Crystallographica, 1965
- Corrections for x-ray absorption by a crystal of arbitrary shape1Zeitschrift für Kristallographie, 1965
- Significance tests on the crystallographic R factorActa Crystallographica, 1965
- Angular Momentum Compensation in Narrow Linewidth FerrimagnetsJournal of Applied Physics, 1965
- Scattering factors computed from relativistic Dirac–Slater wave functionsActa Crystallographica, 1965
- Anomalous dispersion corrections computed from self-consistent field relativistic Dirac–Slater wave functionsActa Crystallographica, 1965
- The secondary extinction correctionActa Crystallographica, 1963
- Least squares refinement of the structure of gadolinium-iron garnet Gd3Fe2Fe3O12Acta Crystallographica, 1961
- Parameter interaction in least squares structure refinementActa Crystallographica, 1961
- The interaction of magnetic ions in Gd3Mn2Ge2GaO12and related garnetsJournal of Physics and Chemistry of Solids, 1959