Light Scattering from Chemically Reactive Fluids. II. Case with Diffusion

Abstract

The thermodynamic approach for light scattering developed in a previous paper is extended to include the diffusion process. The results for zero angle are the same as stated before [B. J. Berne and H. L. Frisch, J. Chem. Phys. 47, 3675 (1967); L. Blum and Z. W. Salsburg, ibid. 48, 2292 (1968)], that is, the only remaining contribution to the central Rayleigh line is due to the chemical reactions.