Origin of Strong Chiroptical Activities in Films of Nonafluorenes with a Varying Extent of Pendant Chirality

Abstract

Novel nonafluorenes with a varying extent of pendant chirality were synthesized for an investigation of the origins of chiroptical activities in neat films. Thermal annealing of 4-μm-thick sandwiched films and of 90-nm-thick spin-cast films, all on surface-treated substrates, produced monodomain glassy films characterized as a right-handed cholesteric stack with a helical pitch length ranging from 180 to 534 nm and from 252 to 1151 nm, respectively. The observed strong circular dichroism (CD) and g_e as functions of helical pitch length in single-substrate monodomain glassy cholesteric films were quantitatively interpreted with a circularly polarized fluorescence theory accounting for light absorption, emission, and propagation in a cholesteric stack. Although intertwined molecular helices were likely to be present, cholesteric stacking of rodlike molecules seemed to be the predominant contributor to the strong chiroptical activities. All the cholesteric stacks comprising a polydomain glassy film on an untreated substrate were found to contribute to CD and g_e largely to the same extent as in a monodomain film. A circularly polarized blue organic light-emitting diode containing a nonafluorene film resulted in a g_e of 0.35 with a luminance yield of 0.94 cd/A at 20 mA/cm², the best performance to date.