A polyoxometallate-templated coordination polymer: synthesis and crystal structure of [Cu3(4,4′-bipy)5(MeCN)2]PW12O40·2C6H5CN

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Abstract
The spherical phosphotungstate ion, PW12O40 3−, has been used as a non-coordinating anionic template for the construction of a novel, three-dimensional Cu(I) coordination polymer.