How to stop a molecular rotator. Mössbauer spectroscopic studies on (η-benzene)(η-cyclopentadienyl)iron(II) hexafluorophosphate in the presence and absence of high pressure
- 1 January 1996
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 1,p. 11-12
- https://doi.org/10.1039/cc9960000011
Abstract
Application of a pressure of 1.79 GPa, at room temperature on (η-benzene)(η-cyclopentadienyl)iron(II) hexafluorophosphate is shown to arrest the dynamic reorientation of the cations; the effect of pressure is studied using Mössbauer spectroscopy.Keywords
This publication has 13 references indexed in Scilit:
- The synthesis of iron sandwich complexes by microwave dielectric heating using a simple solid CO2-cooled apparatus in an unmodified commercial microwave ovenJournal of Organometallic Chemistry, 1993
- Molecular motion in solids: Mössbauer spectra of [Fe(η-C6H6)(η-C5H5)][AsF6]J. Chem. Soc., Dalton Trans., 1992
- Molecular motion in solids. The Mössbauer spectra of (η-cyclopentadienyl)(η-fluorobenzene)iron(II) saltsJ. Chem. Soc., Dalton Trans., 1991
- Studies of the bonding in iron(II) cyclopentadienyl and arene sandwich compounds. Part 2. Correlations and interpretations of carbon-13 and iron-57 nuclear magnetic resonance and iron-57 mössbauer dataJ. Chem. Soc., Dalton Trans., 1991
- Studies of the bonding in iron(II) cyclopentadienyl and arene sandwich compounds. Part 1. An interpretation of the iron-57 Mössbauer dataJ. Chem. Soc., Dalton Trans., 1990
- The Mössbauer effect and chemistry. Part 9. Molecular motion in solids. The spectra of (η-cyclohexatriene)(η-cyclopentadienyl)iron(II) hexafluorophosphateJ. Chem. Soc., Dalton Trans., 1980
- Anisotropic relaxation of the electric field gradient tensor in the57Fe Mossbauer spectra of a thiourea-ferrocene clathrateJournal of Physics C: Solid State Physics, 1976
- Magnetic susceptibility measurements using a superconducting magnetometerReview of Scientific Instruments, 1974
- Mössbauer Spectra in a Fluctuating Environment II. Randomly Varying Electric Field GradientsPhysical Review B, 1968
- Effect of Pressure on the Mössbauer Resonance in Ferrocene and PyriteThe Journal of Chemical Physics, 1967