Aldol Condensations with Metal(II) Complex Catalysts
- 1 May 1980
- journal article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 53 (5), 1366-1371
- https://doi.org/10.1246/bcsj.53.1366
Abstract
Aldol condensations of aldehydes with ketones catalyzed by the first-row transition metal(II) complexes have been widely studied. Complexes of Co(II), Ni(II), Cu(II), and Zn(II) acetates with 2,2′-bipyridine were effective catalysts to afford cross-aldol condensation products, α,β,-unsaturated ketones, in high yields without any self-condensation products. The reaction of 2-butanone, unsymmetrical aliphatic ketone, with benzaldehyde took place regioselectively to give base-catalyzed-type products.This publication has 7 references indexed in Scilit:
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