The mechanism of hydrolytic polymerization of zirconyl solutions
- 31 January 1990
- journal article
- Published by Springer Nature in Journal of Materials Research
- Vol. 5 (1), 161-162
- https://doi.org/10.1557/jmr.1990.0161
Abstract
Solutions of zirconyl salts can be treated in a variety of ways to precipitate hydrous amorphous ZrO2. The phases formed upon heating these precipitates are described and rationalized based upon a theory of hydrolytic polymerization which had been proposed at an earlier stage.Keywords
This publication has 10 references indexed in Scilit:
- Zirconium oxide crystal phase: The role of the pH and time to attain the final pH for precipitation of the hydrous oxideJournal of Materials Research, 1988
- Crystal structure of hafnia–zirconia mixtures obtained by calcination of hydrous oxide prepared by precipitationJournal of Materials Research, 1988
- Factors influencing the stability of the tetragonal form of zirconiaJournal of Materials Research, 1986
- Hydrous zirconium dioxide: interfacial properties, the formation of monodisperse spherical particles, and its crystallization at high temperaturesJournal of Materials Science, 1985
- Effect of pH on Crystal Phase of ZrO2 Precipitated from Solution and Calcined at 600°CJournal of the American Ceramic Society, 1984
- An electron microscopic study of the hydrolysis products of zirconyl chlorideJournal of Colloid and Interface Science, 1970
- Crystalline Hydrous ZirconiaInorganic Chemistry, 1964
- Structure of the Complex Ion in Aqueous Solutions of Zirconyl and Hafnyl OxyhalidesThe Journal of Chemical Physics, 1960
- Hydrolytic Behavior of Metal Ions. VI. Ultracentrifugation of Zirconium(IV) and Hafnium(IV); Effect of Acidity on the Degree of Polymerization1,2Journal of the American Chemical Society, 1956
- The crystal structure of zirconyl chloride octahydrate and zirconyl bromide octahydrateActa Crystallographica, 1956