Laboratory angular dependence and the recoil-energy spectrum of the products of the reaction F+C6D6→ D+C6D5F
- 1 August 1973
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 59 (3), 1427-1434
- https://doi.org/10.1063/1.1680200
Abstract
The reaction of fluorine atoms with perdeuterobenzene has been studied by the method of crossed molecular beams. In this reaction a long‐lived intermediate complex is formed. Analysis of the kinetic energy distribution of the products and their angular distribution in space cannot be satisfactorily accounted for by the available statistical theories of unimolecular decomposition. The results of this study can be used to infer that randomization of the internal energy of a molecule is not necessarily rapid relative to chemical reaction.Keywords
This publication has 34 references indexed in Scilit:
- Study of the Lifetimes of Individual Vibronic States of the Isolated Benzene MoleculeThe Journal of Chemical Physics, 1971
- Direct Demonstration of Nonrandomization of Internal Energy in Reacting Molecules. Rate of Intramolecular Energy RelaxationThe Journal of Chemical Physics, 1971
- Fluorescence Lifetime of Benzene and Benzene-d6 Vapor Excited to Single Vibronic LevelsThe Journal of Chemical Physics, 1970
- Harmonic Forces Linear Model for Reactions of Cs Atoms with Alkyl IodidesThe Journal of Chemical Physics, 1970
- Crossed-Beam Studies of Energy Dependence of Intermediate Complex Formation in an Ion–Molecule ReactionThe Journal of Chemical Physics, 1969
- The vibrational spectra of mono and para disubstituted halogenobenzenesSpectrochimica Acta Part A: Molecular Spectroscopy, 1969
- Exchange reactions of alkali atoms with alkali halides: a collision complex mechanismDiscussions of the Faraday Society, 1967
- Statistical theory of bimolecular exchange reactionsDiscussions of the Faraday Society, 1967
- Free Radical Reactions Initiated by Ionizing Radiation. II. Rate Constants for Hydrogen Atom Addition Reactions with Mono-olefins, Butadiene and BenzeneJournal of the American Chemical Society, 1962
- The Reactions of Recoil Tritium with Substituted Benzoic AcidsJournal of the American Chemical Society, 1960