The first high oxidation state manganese–calcium cluster: relevance to the water oxidizing complex of photosynthesis
- 25 November 2004
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 1,p. 54-56
- https://doi.org/10.1039/b413680b
Abstract
Synthetic entry has been achieved into high oxidation state Mn–Ca cluster chemistry with the preparation of [Mn13Ca2O10(OH)2(OMe)2(O2CPh)18(H2O)4]; the structure contains [Mn4CaO4] sub-units similar to that found in the photosynthetic water oxidizing complex.Keywords
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