Action De Divers Agents Oxydants Sur Les Germylenes
- 1 January 1979
- journal article
- research article
- Published by Taylor & Francis in Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry
- Vol. 9 (3), 273-288
- https://doi.org/10.1080/00945717908057463
Abstract
Oxidation reactions of germylenes by various oxidizing agents (O2, MnO4K, DMSO, C5H5NO, p.NO2C6H4COOOH) give derivatives of the type (X, Y : halogens, alkyl, phenyl),which polymerize to the corresponding germoxanes . XYGe=O intermediates have been characterized by addition to ethylene oxide, methoxygermane R3GeOMe and condensation reactions with excess of germylene and the formation of germoxanes with Ge-Ge bonds: .Keywords
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