A Comparison of Cationic Zirconium Methyl and Isobutyl Initiators that Contain an Arylated Diamido-Pyridine Ligand for Polymerization of 1-Hexene. Elucidation of a Dramatic “Initiator Effect”
- 29 July 2000
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 122 (32), 7841-7842
- https://doi.org/10.1021/ja000772v
Abstract
No abstract availableThis publication has 22 references indexed in Scilit:
- Taming early transition metals: the use of polydentate amido-donor ligands to create well defined reactive sites in reagents and catalystsChemical Communications, 2000
- Propene Polymerization with the Isospecific, Highly Regiospecificrac-Me2C(3-t-Bu-1-Ind)2ZrCl2/MAO Catalyst. 1. Influence of Hydrogen on Initiation and Propagation: Experimental Detection and Theoretical Investigation of 2,1 Propene Insertion into the Zr−H Bond1Organometallics, 1999
- Synthesis of Titanium, Zirconium, and Hafnium Complexes that Contain Diamido Donor Ligands of the Type [(t-BuN-o-C6H4)2O]2-and an Evaluation of Activated Versions for the Polymerization of 1-HexeneOrganometallics, 1999
- Zirconium Complexes That Contain a Diamido O-Donor Ligand with a Restricted GeometryOrganometallics, 1999
- Significant Zirconium−Alkyl Group Effects on Ion Pair Formation Thermodynamics and Structural Reorganization Dynamics in Zirconocenium AlkylsOrganometallics, 1999
- Synthesis of Zirconium Complexes Containing the Tridentate Diamido Ligands [(t-Bu-d6-N-o-C6H4)2S]2-and [(i-PrN-o-C6H4)2S]2-Organometallics, 1999
- High-Field 13C NMR Characterization of Ethene-1-13C/Propene Copolymers Prepared with Cs-Symmetric ansa-Metallocene Catalysts: A Deeper Insight into the Regio- and Stereoselectivity of Syndiotactic Propene PolymerizationMacromolecules, 1998
- Synthesis of Group 4 Complexes That Contain the Tridentate Diamido/Donor Ligands [(ArylNCH2CH2)2O]2- and Zirconium Complexes That Contain [(ArylNCH2CH2)2S]2- and an Evaluation of Their Activity for the Polymerization of 1-HexeneOrganometallics, 1998
- Diastereoselective Synthesis, Molecular Structure, and Solution Dynamics of meso- and rac-[Ethylenebis(4,7-dimethyl-η5-1-indenyl)]zirconium Dichloride Isomers and Chain Transfer Reactions in Propene Polymerization with the rac IsomerOrganometallics, 1996
- Effects of Regiochemical and Stereochemical Errors on the Course of Isotactic Propene Polyinsertion Promoted by Homogeneous Ziegler-Natta CatalystsMacromolecules, 1994