A Porous Supramolecular Architecture from a Copper(II) Coordination Polymer with a 3D Four-Connected 86 Net
- 18 October 2003
- journal article
- research article
- Published by American Chemical Society (ACS) in Inorganic Chemistry
- Vol. 42 (23), 7531-7534
- https://doi.org/10.1021/ic034846q
Abstract
A novel coordination polymer {[Cu(L1)(L2)(H2O)]·5H2O}n (1), where L1 =1,1‘-(1,4-butanediyl)bis(imidazole) and L2 = m-phthalate anion, has been obtained by using an unusual crystallization process. It crystallizes in the orthorhombic space group Pna21, which belongs to the crystal class mm2, with a = 9.0521(18), b = 15.401(3), and c = 17.141(3) Å, α = β = γ = 90°, V = 2389.7(8) Å3, and Z = 4. The complex 1 composing a porous supramolecular architecture displays unprecedented four-connected topology of an 86 net in coordination polymer chemistry. Thermal gravimetric analysis (TGA) and X-ray powder diffraction (XRPD) patterns for 1 are discussed in detail.Keywords
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