A bifunctional catalyst for carbon dioxide fixation: cooperative double activation of epoxides for the synthesis of cyclic carbonates
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- 30 March 2012
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- Vol. 48 (37), 4489-4491
- https://doi.org/10.1039/c2cc30591g
Abstract
We have developed a very active bifunctional porphyrin catalyst showing a high turnover number (TON = 103 000) for the synthesis of cyclic carbonates from CO2 and epoxides under solvent-free conditions.Keywords
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