AN INVESTIGATION OF THE NUCLEAR RESONANCE ABSORPTION SPECTRUM OF Al27 IN A SINGLE CRYSTAL OF EUCLASE

Abstract

The nuclear magnetic resonance spectrum of Al²⁷ in a single crystal of HBeAlSiO₅ (euclase) in an external magnetic field of 7000 gauss is described. The Al²⁷ nuclei are found to occupy two kinds of lattice sites which differ from each other only in the orientation of the principal axes of the electric field gradient tensors whose eigenvalues are all distinct, but identical at both sites. The absolute value of the quadrupole coupling constant for both groups of Al²⁷ nuclei is found to be 5173 ± 10 kc./sec. and the axial asymmetry parameter of the field gradient tensors at both the lattice positions is 0.698 ± 0.009. The two sets of principal axes are reflections of each other in the (010) plane which is consistent with the symmetry of the proposed crystal structure. The theoretical dependence of the spectrum line frequencies on the applied magnetic field is given for one group of Al²⁷ nuclei and for one orientation of the crystal in fields up to 2000 gauss; the feasibility of checking this experimentally is discussed.