Facile Hydride Ion Abstraction from Enamines, Allylamines and Imines
- 1 January 1980
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 10 (11), 867-871
- https://doi.org/10.1080/00397918008062771
Abstract
The conversion of tertiary amines to iminium ions has been accomplished with such oxidants as mercuric acetate or trityl salts2. We wish to report that hydride ion abstraction can be applied to enamines, allylamines and imines. Treatment of 1 or 3 with trityl tetrafluoroborate (⊘ = phenyl) affords 2 in yields of 91% and 63%, respectively.Keywords
This publication has 5 references indexed in Scilit:
- “Biuret‐trichloride” aus N‐Dichlormethylen‐N, N‐dimethyl‐ammoniumchlorid und DimethylcyanamidAngewandte Chemie, 1973
- Methylenimmoniumsalze durch Hydrid‐Abstraktion aus tertiären AminenEuropean Journal of Organic Chemistry, 1971
- Nitrenium ionsAccounts of Chemical Research, 1970
- Some reactions of triphenylmethyl compounds with boron fluorideCanadian Journal of Chemistry, 1967
- Unsaturated Amines. III. Introduction of α,β-Unsaturation by Means of Mercuric Acetate: Δ1(10)-Dehydroquinolizidine1,2Journal of the American Chemical Society, 1955