THE REACTION OF SULPHURYL CHLORIDE WITH GLYCOSIDES AND SUGAR ALCOHOLS: PART II
- 1 July 1960
- journal article
- Published by Canadian Science Publishing in Canadian Journal of Chemistry
- Vol. 38 (7), 1122-1129
- https://doi.org/10.1139/v60-156
Abstract
The structures of methyl 4,6-dichloro-4,6-dideoxy-α-D-hexoside and methyl "4-chloro-4-deoxy-β-pentoside" (I) have been investigated. The desulphation reaction leading to the formation of the latter compound is described. Replacement of the hydroxyl group at C(4) by a chlorine atom in both compounds is shown to have occurred with inversion of configuration.Keywords
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