Potential Energy Curve of the Excited State of LiH
- 1 January 1938
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 6 (1), 16-18
- https://doi.org/10.1063/1.1750117
Abstract
A method developed by Klein has been applied to obtain the potential energy curve of the excited electronic state of LiH (state V). This curve crosses the Coulombic curve of Li+H— and indicates dissociation of excited LiH into Li(2 P)+H. The effect of this behavior on Mulliken's explanation of the unusual shape of the state V curve is discussed. The interaction of the Li+H— and Li(2 P)·H curves at moderately large interatomic distances is larger than Mulliken's estimate.Keywords
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