[NHMe3][Cu(CS4)]: a two-dimensional network involving an unprecedented μ3-η1:η1:η2 coordination mode of perthiocarbonate to copper(I)

Abstract

The new complex [NHMe₃][Cu(CS₄)], which was obtained by solvothermal synthesis, contains a two-dimensional ² _∞[Cu(CS₄)^–] network consolidated by an unprecedented µ₃-η¹:η¹:η² coordination mode of the perthiocarbonate dianion.