Correlation effects of a phase-diffusing field on two-photon absorption

Abstract

Experimental evidence of field-correlation effects on weak-field two-photon absorption in atomic sodium is presented. In the case of a nearly Lorentzian laser power spectrum the absorption profile has four times the spectral width of the exciting field, in agreement with predictions by Mollow. The measurement is carried out with counterpropagating laser beams to cancel Doppler broadening. The width of the two-photon absorption spectrum is decreased by partially decorrelating the counterpropagating laser beams. Increasing the correlation time of the frequency fluctuations, resulting in a nearly Gaussian laser power spectrum, has also been observed to decrease the width of the absorption spectrum. An extension of the time-dependent second-order perturbation theory to these additional cases yields good agreement.