Relativistic effects on the surface electronic structure of Cu(001): Observation of a spin-orbit-gap surface state

Abstract
A second Cu(001) surface state located near the d-band maximum has been characterized using angle-resolved photoemission. High energy resolution, provided by a new dispersive spectrometer, was necessary to identify and characterize the surface state. At the state, which has odd parity with respect to the (100) mirror plane, lies 65 meV below the d-band maximum, at 2.113 eV binding energy. Comparison with the surface projection of a recently calculated relativistic bulk band structure, indicates that this state lies in an absolute spin-orbit gap. The gap extends along one third of Σ¯ in the surface Brillouin zone.