Aromatic Keto Compounds as Initiators in Photopolymerizations
- 1 November 1972
- journal article
- review article
- Published by Wiley in Angewandte Chemie International Edition in English
- Vol. 11 (11), 974-978
- https://doi.org/10.1002/anie.197209741
Abstract
The present article deals with the primary photochemical reactions of carbonyl compounds commonly used as photoinitiators. It is shown that radical formation results mainly from three processes, i.e. hydrogen abstraction, β‐cleavage, and α‐cleavage. The difference in the suitability of the radicals for chain initiation is discussed.This publication has 28 references indexed in Scilit:
- Photolysis of methoxy-substituted benzoin esters. Photosensitive protecting group for carboxylic acidsJournal of the American Chemical Society, 1971
- Kinetik der Polymerisationsauslösung mit aromatischen pinakolenDie Makromolekulare Chemie, 1971
- Photolysis of benzaldehyde in solution studied by nuclear magnetic resonance spectroscopyJournal of the American Chemical Society, 1970
- Molecular structure and photochemical reactivity. X. Aliphatic hydroxy ketonesJournal of the American Chemical Society, 1969
- Photoreduction of Benzophenone in Methyl 2-Octyl Ether. Effects of Mercaptan, Disulfide, and Oxygen1Journal of the American Chemical Society, 1966
- Perturbation of Singlet-Triplet Transition Energies1Journal of the American Chemical Society, 1965
- Photolysis of Desyl Compounds. A New Photolytic CyclizationJournal of the American Chemical Society, 1964
- PHOTOCHEMICAL SYNTHESES: 9. THE CONVERSION OF DIBENZOYLMETHANE TO TRIBENZOYLETHANECanadian Journal of Chemistry, 1964
- Mechaisms of Photochemical Reactions in Solution. XXVIII.1 Values of Triplet Excitation energies of Selected SensitizersJournal of the American Chemical Society, 1964
- Photoinitiated Diradical Polymerization of Methyl MethacrylateJournal of the American Chemical Society, 1955