A nucleophilic niobium(V) nitride prepared by isocyanate decarbonylation
- 1 January 1997
- journal article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 20,p. 1993-1994
- https://doi.org/10.1039/a704253a
Abstract
Carbon monoxide is lost upon sodium amalgam reduction of [(OCN)Nb{N(R)Ar}3] [R = C(CD3)2CH3, Ar = C6H3Me2-3,5] to give crystallographically characterized [Na{NNb- [N(R)Ar]3}]2, a nucleophilic niobium(V) nitride which reacts with ClP(NMe2)2 and O(SO2CF3)2 to give P- and S-substituted imido complexes, respectively.Keywords
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