Preparation of Novel Poly(aryleneamine)s by Palladium Complex Catalyzed Polycondensation of Dibromobenzenes with Diamines
- 1 December 1996
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 25 (12), 1135-1136
- https://doi.org/10.1246/cl.1996.1135
Abstract
The reaction of aryl dibromides with secondary diamines proceeds smoothly in the presence of a stoichiometric base such as NaOtBu and a catalytic amount of palladium complex, PdCl2(P(o-tolyl)3)2 (P(o-tolyl)3 = tri-o-tolylphosphine), in toluene to give the corresponding new poly(aryleneamine)s.Keywords
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