Relative molecular orbital energies in tetrahedral complexes
- 1 September 1961
- journal article
- research article
- Published by Taylor & Francis in Molecular Physics
- Vol. 4 (5), 395-400
- https://doi.org/10.1080/00268976100100551
Abstract
M.O. theory is used for classifying the energy levels of tetroxo complexes, and linear relations are shown to exist between the M.O. energies (and hence the electro-negativities) and the oxidation number and electron configuration of the central ion. The extent of π-bonding effects is quantitatively studied and compared with the analogous situation in the hexahalides.Keywords
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