Dissociation energy of chlorine monofluoride
- 1 July 1974
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 61 (1), 224-226
- https://doi.org/10.1063/1.1681626
Abstract
Measurements of the equilibrium constant for the gas phase reaction F+Cl2=ClF+Cl by a Cl‐atom chemiluminescence technique yield ΔH°0= −3.27±0.24 kcal/mole. This result settles the existing uncertainty in the spectroscopic determination of D°0(ClF) in favor of the larger value, 60.35 kcal/mole.Keywords
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