Etude paramétrique de l'enrichissement en carbone-13 dans la décomposition polyphotonique de CF3Cl

Abstract

The yield and ¹³C content of the product C₂F₆ were measured following the multiphoton infrared decomposition of CF₃Cl. These factors were studied as a function of the activation frequency ω, of the pressure of CF₃Cl, of the temperature T, and of the incident energy E₀. As in the case of CF₃Br and CF₃I the yield increases according to P²E₀². [Journal translation]