Fluororganische Synthesen V Darstellung und Abwandlung von Chlorfluorcyclopropanen ‐ Ein gezielter Zugang zu Fluorallylalkoholen
- 5 November 1975
- journal article
- research article
- Published by Wiley in Helvetica Chimica Acta
- Vol. 58 (8), 2595-2604
- https://doi.org/10.1002/hlca.19750580844
Abstract
Fluoroorganic Syntheses V. Preparation and Transformation of Chlorofluorocyclopropanes. – A Selective Approach to Fluoroallylic AlcoholsChlorofluorocarbene addition to unsaturated compounds is particularly convenient and efficient in a two‐phase system. This method works satisfactorily even if the olefin carries base‐sensitive substituents. The resultant chlorofluorocyclopropanes can be ring‐opened by silver‐salt assisted acetolysis affording 2‐fluorallylacetates, which yield 2‐fluorallylic alcohols upon saponification.This publication has 24 references indexed in Scilit:
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