Adsorption and Dissociation of Nitric Oxide on the Ru(001) Surface
- 23 October 1978
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review Letters
- Vol. 41 (17), 1181-1184
- https://doi.org/10.1103/physrevlett.41.1181
Abstract
The adsorption of nitric oxide and its dissociation on the Ru(001) surface have been studied through the vibrational energies of the adsorbed layer. The inelastic electron scattering measurements show that two distinct states of molecular NO are adsorbed at 130 K. The dissociation of a bridged NO is complete at 316 K, whereas a linear form remains on the surface until 500 K. This is explained by a difference in activation energies for dissociation of NO and by the blocking of sites by nitrogen and oxygen adatoms.Keywords
This publication has 12 references indexed in Scilit:
- Chemisorption of nitric oxide on ruthenium (101)Surface Science, 1978
- Collective vibrational modes of adsorbed COThe Journal of Chemical Physics, 1978
- Chemisorption and decomposition of nitric oxide on rutheniumSurface Science, 1977
- The interactions of nitric oxide and oxygen with Ru(101̄0)Surface Science, 1977
- Comparison of cross sections in high resolution electron energy loss spectroscopy and infrared reflection spectroscopySurface Science, 1977
- Adsorption of NO and CO on aSurface Science, 1977
- Reaktionen von nitrosylkomplexen : IV. Neue cyclopentadienyl-μ-nitrosyl-kobalt-komplexeJournal of Organometallic Chemistry, 1975
- An UV photoemission study of NO and CO adsorption on Pt (100) and Ru (1010) surfacesSurface Science, 1975
- Coordination chemistry of nitric oxideAccounts of Chemical Research, 1975
- An Infrared Study of the Directive Influences by Ligands in Nitrosylruthenium ComplexesInorganic Chemistry, 1966