Temperature dependence of the nonergodicity parameter in polybutadiene in the neighborhood of the glass transition
- 11 June 1990
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review Letters
- Vol. 64 (24), 2921-2924
- https://doi.org/10.1103/physrevlett.64.2921
Abstract
Using neutron-spin-echo and time-of-flight spectroscopy we have investigated the precise temperature dependence of the elastic (nonergodic) fraction in the spectrum of density fluctuations of the glass-forming polymer polybutadiene. With increasing temperature we found a critical decrease of the normalized elastic intensity following closely the (-T behavior predicted by the mode-coupling theory. The critical temperature was determined to be =216±1 K, i.e., 35 K above .
Keywords
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