Abstract
The existence of a relation between the depression of the freezing point, produced by dissolving an acid or a salt in water, and the electrolytic conductivity of the solution thus obtained was pointed out by Arrhenius in 1887, and has been the subject of much experiment and discussion since that date. As is well known, the facts of electrolysis indicate that an electric current, when passing through a solution, is associated with a passage in opposite directions of the constituents of the salt. Faraday called these mobile parts ions. The number of the ions depends on the chemical nature of the salt, and is usually indicated by its formula. Thus for one molecule of potassium chloride we have two ions, the potassium travelling in one direction and the chlorine in the other. For barium chloride or sulphuric acid we have three ions, and, since the electric charge of an ion is proportional to its valency, the electrically equivalent weights of these substances are represented by ½BaCl 2 and ½H 2 So 4 , respectively.