The determination of heats of mixing
- 7 May 1952
- journal article
- Published by The Royal Society in Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences
- Vol. 212 (1110), 406-425
- https://doi.org/10.1098/rspa.1952.0091
Abstract
A calorimeter has been designed for measuring the heats of mixing of binary liquid systems, which eliminates the need to correct for changes in the composition of the vapour phase on mixing. Improved accuracy has thus been obtained. Heats of mixing have been measured for the three binary systems formed from the three components carbon tetrachloride, chloroform and methylene chloride, and also for the systems benzene + carbon tetrachloride and benzene + ethylene dichloride. Reports that the last system is ideal have been disproved.Keywords
This publication has 4 references indexed in Scilit:
- Solutions of NonelectrolytesAnnual Review of Physical Chemistry, 1950
- Thermodynamic properties of mixtures of alkanes differing in chain length. I. Heats of mixingRecueil des Travaux Chimiques des Pays-Bas, 1950
- Vapor-Liquid Equilibrium. V. Carbon Tetrachloride-Benzene Mixtures1Journal of the American Chemical Society, 1940
- A CALORIMETER FOR HEATS OF MIXING AT ELEVATED TEMPERATURES1Journal of the American Chemical Society, 1924