Ion-neutralization spectroscopy

Abstract

The ion-neutralization spectroscopy (INS) is discussed in comparison with other spectroscopies of solids. It is shown that INS probes the local density of states of the solid at or just outside the solid surface. It is believed that this accounts for the clear-cut differences between INS results and those of other spectroscopies. Because of its unique specificity to the surface region INS is particularly useful in studying the surface electronic structures of atomically clean surfaces and of surfaces having ordered arrays of known atoms adsorbed upon them. In the latter case INS determines a portion of the molecular orbital spectrum of surface molecules formed from the adsorbed foreign atom and surface atoms of the bulk crystal. Such spectra provide information on local bonding symmetry and structure and electrical charging within the surface molecule which is as yet unavailable by any other method. INS is the first attempt to base a spectroscopy of electronic states on a two-electron process. More recent work on experimental and mathematical problems which such a spectroscopy entails are also briefly mentioned in this paper.