N–Hvis. C–H activation; a major ligand size effect
- 1 January 1993
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Chemical Communications
- No. 3,p. 318-319
- https://doi.org/10.1039/c39930000318
Abstract
The complexes trans-[Ir(PR3)2(C2H4)]Cl (3, R = Et; 4, R = Pri) exhibit entirely different reactivity pathways with ammonia, whereas 3 undergoes N–H oxidative addition, 4 coordinates ammonia and undergoes C–H activation of the ethylene ligand at 25 °C to yield an hydrido vinyl complex, and phosphine metallation at 80 °C.Keywords
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