Binuclear Metal Complexes. III. Preparation and Properties of Mononuclear and Binuclear Copper(II) and Nickel(II) Complexes of New Macrocycles and Their Related Ligands
- 1 June 1972
- journal article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 45 (6), 1759-1764
- https://doi.org/10.1246/bcsj.45.1759
Abstract
The syntheses and properties of copper(II) and nickel(II) complexes of N,N′-alkylenebis(3-formyl-5-methylsalicylaldimine (alkylene=ethylene, propylene, or trimethylene) are described. By the reaction of these complexes with other alkylenediamines (ethylenediamine or trimethylenediamine), mononuclear copper(II) and nickel(II) complexes of new N4O2-type macrocycles have been synthesized. These complexes react with additional copper(II) or nickel(II) ions to form binuclear copper(II) or nickel(II) complexes. The geometries and properties of these new complexes are discussed.This publication has 22 references indexed in Scilit:
- Synthesis of a two-metal macrocyclic systemInorganic Chemistry, 1971
- Binuclear Copper(II) Complexes Derived From 3-Formyl-5-methyIsaIicyIaldehyde and GlycineBulletin of the Chemical Society of Japan, 1971
- Copper(II) Complexes of 3-Formyl-5-methylsalicylaldehyde and Its Schiff Bases with Alkyl AminesBulletin of the Chemical Society of Japan, 1970
- Complexes of binucleating ligands I. Two novel binuclear cupric complexesInorganic and Nuclear Chemistry Letters, 1970
- Metal complexes as ligands — V[1]: Binuclear copper complexes derived from bidentate Schiff base complexesJournal of Inorganic and Nuclear Chemistry, 1968
- Metal complexes as ligands—IV [1,2,3]Journal of Inorganic and Nuclear Chemistry, 1968
- Metal complexes as ligands III1 structures of BI- and tri-nuclear compounds derived from salicylaldimine complexesInorganic and Nuclear Chemistry Letters, 1968
- Infrared spectra of 15N substituted copper complexesInorganic and Nuclear Chemistry Letters, 1967
- Physico-chemical properties of co-ordinating compounds—IIISpectrochimica Acta, 1963
- The Stereochemistry of Metal Chelates with Polydentate Ligands. Part IJournal of the American Chemical Society, 1955