Synthesis of 1,2-dichlorotetrafluoro- and 1,2,4-trichlorotrifluorobenzenes
- 1 April 2012
- journal article
- Published by Pleiades Publishing Ltd in Russian Journal of Organic Chemistry
- Vol. 48 (4), 536-543
- https://doi.org/10.1134/s1070428012040124
Abstract
1,2-Dichlorotetrafluorobenzene was obtained by reactions of chlorine with 5,6,7,8-tetrafluoro-1,4-benzodioxane and with a mixture of 3,4,5,6-tetrafluorophthaloyl chloride and 3,3-dichloro-4,5,6,7-tetrafluorophthalide at 500–550°C. Pyrolysis of pure 3,4- and 2,5-dichlorotrifluorobenzenethiols, as well as of a mixture of 3,4-, 2,4-, and 2,5-dichlorotrifluorobenzenethiols, in the presence of chlorine at 400–415°C in a flow system gave difficultly accessible 1,2,4-trichlorotrifluorobenzene.Keywords
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