Theory of E.P.R. in low-spin ferric haemoproteins
- 1 January 1971
- journal article
- research article
- Published by Taylor & Francis in Molecular Physics
- Vol. 21 (1), 135-139
- https://doi.org/10.1080/00268977100101251
Abstract
Difficulty is found in fitting experimental g values for low-spin ferric haemoproteins to formulae based on a pure t 2 5 configuration. This is discussed and it is shown that it is almost certainly mainly due to neglect of configuration interaction with excited t 2 4 e states, a mechanism which was originally discussed by Thornley [8] for octahedral iridium complexes.Keywords
This publication has 12 references indexed in Scilit:
- An Analysis of the Electron Spin Resonance of Low Spin Ferric Heme CompoundsBiophysical Journal, 1970
- The magnetic properties of (IrX6)2- complexesJournal of Physics C: Solid State Physics, 1968
- Transformations of a spin-Hamiltonian induced by reassignments of fictitious spin statesMolecular Physics, 1967
- PorphyrinsTheoretical Chemistry Accounts, 1966
- Some investigations in the theory of open-shell ionsMolecular Physics, 1960
- Sign ofin Magnetic Resonance, and the Sign of the Quadrupole Moment ofPhysical Review Letters, 1959
- Binding in Hæmoglobin Azide as Determined by Electron Resonance: Theory of Electron Resonance in Ferrihæmoglobin AzideNature, 1957
- Paramagnetic Resonance in some Complex Cyanides of the Iron Group II. TheoryProceedings of the Physical Society. Section B, 1956
- On the Absorption Spectra of Complex Ions. IJournal of the Physics Society Japan, 1954
- On the magnetic properties of covalentXY6complexesProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1953