Influence of Anionic Sites In Solvent Polymeric Membranes On Potential Response and Ion-Selectivity Behavior
- 1 April 1989
- journal article
- Published by Taylor & Francis in Analytical Letters
- Vol. 22 (5), 1171-1184
- https://doi.org/10.1080/00032718908051399
Abstract
A generalized but still rather compact theoretical description of the potentiometric response behavior of membranes that contain any number of electrically neutral ionophores and electrically charged ligands or ion-exchange sites is presented. the discussion of the limiting cases exemplifies that the pronounced high ion selecrivities observed for several ion sensors are favored by the fortuitous coincidence of special boundary conditions fulfilled for such systems.Keywords
This publication has 19 references indexed in Scilit:
- Plasticized poly(vinyl chloride) properties and characteristics of valinomycin electrodes. Current-time responses to voltage stepsAnalytical Chemistry, 1988
- Responses of site-controlled, plasticized membrane electrodesAnalytical Chemistry, 1988
- Nature of anionic sites in plasticized poly(vinyl chloride) membranesAnalytical Chemistry, 1987
- Donnan exclusion failure in low anion site density membranes containing valinomycinJournal of Electroanalytical Chemistry and Interfacial Electrochemistry, 1987
- Plasticized poly(vinyl chloride) properties and characteristics of valinomycin electrodes. 2. Low-frequency, surface-rate, and Warburg impedance characteristicsAnalytical Chemistry, 1986
- Plasticized poly(vinyl chloride) properties and characteristics of valinomycin electrodes. 1. High-frequency resistances and dielectric propertiesAnalytical Chemistry, 1986
- Cation‐Response Mechanism of Neutral Carrier Based Ion‐Selective Electrode MembranesHelvetica Chimica Acta, 1986
- Neutral Carrier Based Ion-Selective ElectrodesPublished by Elsevier ,1983
- Mechanism of neutral carrier mediated ion transport through ion-selective bulk membranesAnalytical Chemistry, 1977
- Transport properties of neutral carrier on selective membranesAnalytical Chemistry, 1976