Statistics of the entanglement of polymers: Concentration effects

Abstract

Central concepts of the reptation model of polymer relaxation by disentanglement are the confining tube, the primitive path, and the entanglement net. These are given more precise definitions and are expounded upon here. The entanglement net is regarded as the set of primitive paths of the molecules. The scaling relation connecting distance between entanglements and concentration is derived by a self‐consistency argument. Explicit results on probability distributions characterizing unentangled loops and primitive path lengths are derived. The polymers are modeled as random walks in a regular entanglement net. Results are presented as a function of the spacing between entanglements.