Synthesis and Nucleophilic Behavior of cis-[M(C6F5)2(Ph2PCHPPh2)]- (M = Pd, Pt): C-Alkylation, Metalation, and Halogenation of Coordinated Bis(diphenylphosphino)methane. X-ray Crystal Structure of [Pt(C6F5)2(Ph2PCHIPPh2)]·C5H12
- 9 January 1996
- journal article
- Published by American Chemical Society (ACS) in Organometallics
- Vol. 15 (1), 309-316
- https://doi.org/10.1021/om950457v
Abstract
No abstract availableThis publication has 34 references indexed in Scilit:
- Polyfunctional ligands: comparative oxidative coupling of [E(PPh2)2]–(E = CH, N) with iodineJournal of the Chemical Society, Chemical Communications, 1995
- Metal-Assisted Synthesis of dppm-Derived Diphosphines Involving the Formation of Three New Types of Frameworks around Carbon: P2CHX, [P2CX]-, and P2CX2 (X = Halogen)Organometallics, 1994
- Zirconocene derivatives with phosphinomethanide ligands: metal-promoted ligand metalations: tuning of regioselectivity and formation of novel zirconaphosphaheterocyclesOrganometallics, 1993
- Carbene complexes from coordinated bis(diphenylphosphino)methane. Synthesis and X-ray structure determination of the remarkable heterotrimetallic derivative [{Fe(CNPh)4((PPh2)2C)}2Hg]I2Journal of the Chemical Society, Chemical Communications, 1993
- Carbon-fluorine bond cleavage in C6F5X arenes by carbonyl-stabilized phosphorus ylides. Synthesis of Ph3P:C(C6F4X-4)R (X=CN or NO2). Crystal and molecular structure of Ph3P:C(C6F4CN-4)CO2EtJournal of the American Chemical Society, 1993
- Controlled double metalation of coordinated dppm in manganese(I) complexes. The ligand [(PPh2)2C]2- as a building block in the syntheses of heterometallic speciesOrganometallics, 1992
- Pentafluorophenyl complexes of palladium and platinum containing chelating, unidentate, or bridging Ph2PCH2PPh2ligandsJ. Chem. Soc., Dalton Trans., 1987
- Ambivalentes Verhalten in α‐Stellung lithiierter Phosphane gegenüber ElektrophilenEuropean Journal of Inorganic Chemistry, 1984
- Synthesis of [M(CO)4(Ph2PCHRPPh2)](M = Cr, Mo, or W; R = COPh or COC6H4Me-p) and photochemically induced reactions of the complex [W(CO)4{Ph2PCH(COPh)PPh2}]: crystal structures of the complexes [W(CO)4{Ph2POC(Ph)CHPPh2}] and [W(CO)4(PPh2OH)(PPh2CH2COPh)]J. Chem. Soc., Dalton Trans., 1984
- Alkylation and acylation of co-ordinated tertiary phosphines: the nucleophilic substitution of the carbanions derived from [M(CO)4(Ph2PCH2PPh2)](M = Cr, Mo, or W)Journal of the Chemical Society, Chemical Communications, 1982