Dehydration of the nanoporous coordination framework Eriii[Coiii(CN)6]·4(H2O): single crystal to single crystal transformation and negative thermal expansion in Eriii[Coiii(CN)6]
- 20 March 2006
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 17,p. 1857-1859
- https://doi.org/10.1039/b601344a
Abstract
Desorption of bound and unbound water molecules from the nanoporous coordination framework ErIII[CoIII(CN)6]·4H2O to form the apohost, ErIII[CoIII(CN)6], proceeds via a single crystal to single crystal transformation in which the Er(III) cations change from 8- to 6-coordinate; dehydration results in a striking change in the thermal expansion properties.Keywords
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