Temperature Dependence of the Elastic, Piezoelectric, and Dielectric Constants of Lithium Tantalate and Lithium Niobate

Abstract

The elastic, piezoelectric, and dielectric constants, and their temperature dependence within the range 0°–110°C, have been determined for single crystals of lithium tantalate and lithium niobate. For each material, the constants were extracted from a combination of many ultrasonic phase‐velocity measurements, the measured resonant and antiresonant frequencies of a single length‐extensional bar resonator, and the measured low‐frequency capacitances of two thin flat‐plate specimens. For lithium tantalate, the normalized first temperature derivatives of the elastic constants range from −0.4 to −6.7×10⁻⁴/°C, while the derivatives for the piezoelectric stress constants range from −1.3 to +1.5×10⁻⁴/°C. In the case of lithium niobate, the elastic constant temperature derivatives are all on the order of −2×10⁻⁴/°C, while the piezoelectric temperature derivatives are all positive in the range 0.8–8.9×10⁻⁴/°C. The dielectric or permittivity temperature derivatives are positive for both materials.