Proton Magnetic Resonance Studies of Polycrystalline Uranium Oxide Hydrates. I. β-UO32H2O
- 1 April 1962
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 36 (7), 1695-1699
- https://doi.org/10.1063/1.1701253
Abstract
The broad‐line protonmagnetic resonance spectra of polycrystalline samples of the compound formulated empirically as β—UO32H2O have been investigated in the temperature range 77°—350°K. The second moment of the absorptionspectrum at 77°K indicates that some of the protons in the crystal are not present in water of crystallization and an analysis of the line shape shows that the compound is the trihydrate of pyrouranic acid, U2O5(OH)2·3H2O. The chemical properties of the compound are accounted for on the basis of this formula.Keywords
This publication has 16 references indexed in Scilit:
- Some evidence for the presence of uranic acid in uranium trioxide-water systemsJournal of Inorganic and Nuclear Chemistry, 1959
- Studies on the Hydrolysis of Metal Ions. 24. Hydrolysis of the Uranyl Ion, UO2+2, in Perchlorate Self-Medium.Acta Chemica Scandinavica, 1959
- The structure of U3O8determined by neutron diffractionActa Crystallographica, 1958
- X-Ray Investigations on Uranyl Hydroxides. I. The Crystal Structure of beta-UO2(OH)2.Acta Chemica Scandinavica, 1956
- Crystal chemical studies of the 5f-series of elements. XXIII. On the crystal chemistry of uranyl compounds and of related compounds of transuranic elementsActa Crystallographica, 1954
- Apparatus for Nuclear Magnetic ResonanceReview of Scientific Instruments, 1953
- Nuclear Magnetic Resonance Modulation CorrectionPhysical Review B, 1953
- Some Chemical and Physical Properties of Uranium PeroxideJournal of the American Chemical Society, 1950
- The Dipolar Broadening of Magnetic Resonance Lines in CrystalsPhysical Review B, 1948
- Über die Hydrate des Urantetroxyds und UrantrioxydsZeitschrift für anorganische und allgemeine Chemie, 1922