Highly Selective Sorption and Luminescent Sensing of Small Molecules Demonstrated in a Multifunctional Lanthanide Microporous Metal–Organic Framework Containing 1D Honeycomb‐Type Channels
- 24 January 2013
- journal article
- research article
- Published by Wiley in Chemistry – A European Journal
- Vol. 19 (10), 3358-3365
- https://doi.org/10.1002/chem.201203487
Abstract
A rare, robust microporous lanthanide metal–organic framework with 1D honeycomb-type channels is presented. Excellent adsorption capabilities for N2, H2, and CO2 and significant selective sorption of CO2 over N2 and CH4 were observed. Moreover, the guest-dependent luminescent behavior of these lanthanide materials shows a potential use for the sensing of small-molecule pollutants such as benzene and acetone.Keywords
Funding Information
- MOST (973 program, 2012CB821702)
- NSFC (90922032, 21171100)
- MOE (20100031110009)
- 111 Project (B12015)
This publication has 91 references indexed in Scilit:
- Lanthanide homometallic and d–f heterometallic MOFs from the same tripodal ligand: structural comparison, one photon (OP) vs. two photon (TP) luminescence and selective guest adsorption behaviorJournal of Materials Chemistry, 2012
- Lanthanide-Thiophene-2,5-dicarboxylate Frameworks: Ionothermal Synthesis, Helical Structures, Photoluminescent Properties, and Single-Crystal-to-Single-Crystal Guest ExchangeInorganic Chemistry, 2011
- Preparation and photoluminescence properties of functionalized silica materials incorporating europium complexesOptical Materials, 2011
- Enhanced carbon dioxide capture upon incorporation of N,N′-dimethylethylenediamine in the metal–organic framework CuBTTriChemical Science, 2011
- Luminescent Functional Metal–Organic FrameworksChemical Reviews, 2011
- Enhanced CO2 Binding Affinity of a High-Uptake rht-Type Metal−Organic Framework Decorated with Acylamide GroupsJournal of the American Chemical Society, 2010
- Synthesis, Structures, and Luminescent and Magnetic Properties of Ln−Ag Heterometal−Organic FrameworksInorganic Chemistry, 2009
- Structures and luminescent properties of a series of Ln–Ag heterometallic coordination polymersCrystEngComm, 2009
- Homochiral Crystallization of Microporous Framework Materials from Achiral Precursors by Chiral CatalysisJournal of the American Chemical Society, 2008
- Three-Dimensional Lanthanide Thiophenedicarboxylate Framework with an Unprecedented (4,5)-Connected TopologyCrystal Growth & Design, 2008